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Product Name: H2Opu
Issue Date: May 2008

This product is classified as HAZARDOUS according to criteria of the National Occupational Health and Safety Commission Australia. Not classified as a DANGEROUS GOOD according to the Australian Dangerous Goods (ADG) Code.

 

COMPANY DETAILS
Company Name: Know-How Waterproofing Pty Ltd (ABN 14 101 886 051)
Address Unit 1/708 Boundary Rd, COOPERS PLAINS, QLD 4108, Australia.
Tel/Fax 07 - 32741000 / 07 - 32741006
 

IDENTIFICATION
 
Product Name H2Opu
Other Names H2Opu
Shipping name   None allocated
Manufacturer's Product Code None allocated
UN Number None allocated
Dangerous goods None allocated
Packing group None allocated
Haz-chem Code  None allocated
Poisons Schedule  Not Scheduled
Product Use Polyurethane coatings
 

 
PYSICAL DATA
 
Appearance White/opaque liquid
Melting Point  Not Measured
Boiling point 100 C
Vapour Pressure Not measured
Specific Gravity 
Flash Point  Not applicable
Flamm. Limit LEL  Not applicable
Solubility in Water   100% Dilutable
 

OTHER PROPERTIES
 
Volatile Component:
33%
Autoignition Temp: Not applicable
Vapour Density:   
Heavier than air
PH Value   Not applicable
Odour:
Faint amine odour
Stability:
Stable under normal conditions of storage and handling.
Haz. Polymerization: Will not occur.
Materials to Avoid: Avoid contact with acids and anhydrides.
 

INGREDIENTS
 
Ingredients  Chemical Entity CAS Proportion  
  Urethane polymer Proprietary 30 - 60%
  N-Methyl-2-pyrrol idone
872-50-4 1 – 5%
  Triethylamine 121-44-8 1 – 5%
  Butyl Di-Glycol Ether   1 – 5%
  Cellosolve   1 – 5%
  Other ingredients determined not to be hazardous
  Balance
 

HEALTH HAZARD INFORMATION
 
Heath Effects
Acute - Swallowed Ingestion of this product may irritate the gastric tract causing nausea and vomiting.
Acute - Eye  Irritating to eyes. On eye contact this product will cause tearing, stinging, blurred vision, and redness.
Acute - Skin Irritating to skin resulting in redness and itching.
Acute - Inhaled   Irritating to respiratory system. Inhalation of product vapours will cause irritation of the nose, throat and respiratory system.
Hazards Identification

Classified as hazardous according to the criteria of NOHSC.
Not classified as a dangerous good according to the ADG Code.

Risk phrases:
R36/37/38 Irritating to eyes, respiratory system and skin.

Safety phrases:
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S37/39 Wear suitable gloves and eye/face protection.
S51 Use only in well ventilated areas.

Chronic Prolonged or repeated skin contact may lead to allergic contact dermatitis.
 

FIRST AID
 
Swallowed Do NOT induce vomiting. Wash out mouth with water. If symptoms develop
Seek medical attention.
Eye  If contact with the eye(s) occurs, wash with copious amounts of water
Holding eyelid(s) open. Take care not to rinse contaminated water into the non-affected eye. If symptoms persist seek medical attention.
Skin Wash affected area thoroughly with soap and water. Remove contaminated clothing and wash before reuse or discard. If symptoms develop seek medical attention.
Inhaled Remove the source of contamination or move the victim to fresh air. Ensure airways are clear and have qualified person give oxygen through a face mask if breathing is difficult. If symptoms develop seek medical attention.
First Aid Facilities Eye wash and normal washroom facilities.
Other Information  For advice, contact a Poisons Information Centre.  Phone 131 126 or a doctor.
   
Advice to Doctor Treat symptomatically.
 

PRECAUTIONS FOR USE
 
   
Exposure Limits No exposure limits have been established for this material by the National Occupational Health And Safety Commission (NOHSC), however for theconstituents;
 
SUBSTANCE
TWA ppm mg/m³
STEL ppm mg/m³
N-methyl-2-pyrrolidone
25     103
75    309
Triethylamine
3        12
5      20
     
Other Exposure Info
TWA - the Time-Weighted Average airborne concentration over an eight-
Hour working day, for a five-day working week over an entire working life.
STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight-hour workday.
Eng. Controls
Use with good general ventilation. If mists or vapours are produced local exhaust ventilation should be used.

 

 
TWA Work safe Exposure Standard Time Weighted Average (TWA): None established
STEL Short Term Exposure Limit (STEL): None Established
Engineering Controls Use local exhaust ventilation with a minimum capture velocity of 0.5 metres/second at the point of vapour evolution. Refer to Australian Standards AS1688.
   
PERSONAL PROTECTION  
   
Respirator Type
(AS 1716)
If engineering controls are not effective in controlling airborne exposure then respiratory protective equipment should be used suitable for protecting against airborne contaminants. Final choice of appropriate breathing protection is dependant upon actual airborne concentrations and the type ofbreathing protection required will vary according to individual circumstances. Expert advice may be required to make this decision. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and maintenance of Respiratory Protective Devices; and AS/NZS 1716,  Respiratory Protective Devices.
Eye Protection Safety glasses with side shields, goggles or full-face shield as appropriate            recommended. Final choice of appropriate eye/face protection will vary according to individual circumstances i.e. methods of handling orengineering controls and according to risk assessments undertaken. Eye protection should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications.
Glove Type Wear gloves of impervious material. Final choice of appropriate gloves will vary according to individual circumstances i.e. methods of handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance.
Clothing Wear appropriate clothing including chemical resistant apron where clothing
is likely to be contaminated. It is advisable that a local supplier of personal
protective clothing is consulted regarding the choice of material.
Other Information
Biological Limit Values: No biological limit allocated.
   
Flammability
 
Fire Hazards
This product is non-flammable. However, following evaporation of aqueous component, the dried residue may burn if ignited.
 

SAFETY HANDLING INFORMATION
 
Storage and Transport
Storage Precautions Store in a cool, dry, well-ventilated area, out of direct sunlight. Store between 12°C and 35°C. Keep containers closed when not in use. Store away from oxidising agents and foodstuffs.
Transport Not classified as a Dangerous Good, according to the Australian Code for The Transport of Dangerous Goods by Road and Rail.
Handling Use in a well ventilated area. Build up of mists or vapours in the atmosphere must be prevented. Avoid breathing in mists or vapours. When dealing with large quantities, repeated or prolonged skin exposure without protection should be prevented in order to lessen the possibility of skin disorders. It is essential that all who come into contact with this material maintain high standards of personal hygiene ie. washing hands prior to eating, drinking, smoking or using toilet facilities.
   
Spills and Disposal
Accidental Release Measures
Slippery when spilt - avoid accidents. Increase ventilation. Evacuate all unnecessary personnel. Wear protective clothing to minimise skin and eye
exposure. If possible contain large spills, absorb with inert absorbent such as vermiculite and place in suitably labelled steel container. Mop up material and place into the same container. Hose down residues or minor spills with excess water. If large quantities of this material enter the waterways contact the Environmental Protection Authority, or your local Waste Management            Authority.
Disposal Considerations
Dispose of waste according to federal, EPA and state regulations.
   
FIRE/EXPLOSION HAZARD
Fire/Explos. Hazard This product is non-flammable. However, following evaporation of aqueous component, the dried residue may burn if ignited.
Hazardous Combustion Products
Under fire conditions this product may emit toxic and/or irritating fumes including carbon monoxide, carbon dioxide and oxides of nitrogen.
Hazardous Decomposition or Byproducts
Thermal decomposition may result in the release of toxic and/or irritating or fumes including carbon monoxide, carbon dioxide and oxides of nitrogen.
Fire Fighting Precautions
Fire fighters should wear full protective clothing and self-contained breathing apparatus (SCBA) operated in positive pressure mode.
Extinguishing Media
Water spray, foam, dry chemcial and carbon dioxide.
Hazardous Reaction
May react with acids and anhydrides.
Conditions to Avoid
Heat, direct sunlight, open flames or other sources of ignition. Avoid temperatures above 46°C.
 
OTHER INFORMATION
 
Toxicology

No toxicity data is available for this specific product, however toxicity data for constituents are stated below:

N-methyl-2-pyrrolidone
LD50 (oral, rat): 3,914 mg/kg
LD50 (dermal, rabbit): 8,000 mg/kg

Triethylamine
LC50 (inhalation, rat): 1,000 ppm/4H
LD50 (oral, rat): 460 mg/kg
Ld50 (dermal, rabbit): 570 µL/kg

Environ. Protection Do not allow product to enter drains, waterways or sewers.
Risk Statement R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statement S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice.
S37/39 Wear suitable gloves and eye/face protection.
S51 Use only in well ventilated areas.
Hazard Category
Irritant
Ecotoxicity
No data is available for this material.
Persistence /Degradability
No data is available for this material.
Mobility
No data is available for this material.
SDS History
MSDS created: April 2009
 
CONTACT POINT  
Contact

For further information ask for:
Know How Agencies P/L

1/32 Success Street Acacia Ridge QLD 4110

Ph 07 - 32741000 / Fax 07-32741006

For specialist advice in emergencies: 1800 033 111

Regulatory Affairs Manager Phone 07 - 32741000
 
GENERAL
 
This MSDS summarises at the date of issue our best knowledge of the health and safety hazard information of this product, and in particular how to safely handle and use this product in the workplace. Since Know How Concrete Technologies and its subsidiaries cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this company.
 

End of MSDS

 
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